The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Home

Cross Sections

Quantum Yields

Errata

Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+Br,I / CH2BrO2 / Nielsen(1991)_298K_220-350nm

DATAFILE: CH2BrO2_Nielsen(1991)_298K_220-350nm.txt
NAME: bromomethylperoxy radical
FORMULA: CH2BrO2
AUTHOR(YEAR): Nielsen(1991)
T: 298K
λ: 220-350nm
BIBLIOGRAPHY: O.J. Nielsen, J. Munk, G. Locke, and T.J. Wallington, "Ultraviolet absorption spectra and kinetics of the self-reaction of CH2Br and CH2BrO2 radicals in the gas phase at 298 K", J. Phys. Chem. 95, 8714-8719 (1991); DOI: 10.1021/j100175a054
COMMENTS: A pulse radiolysis (SF6/O2/CH3Br mixtures) transient UV absorption spectrometer was used to study the UV absorption spectrum of the CH2BrO2 radical

Presumably different radical species were present in the reaction mixture, as suspected by

J. Sehested, M. Bilde, T. Møgelberg, T.J. Wallington, and O.J. Nielsen, "Kinetics and mechanism of the reaction of F atoms with CH3Br," J. Phys. Chem. 100, 10989- 10998 (1996)

Search cross sections

Species search:
Identifier search:
Reference search:
Full text search:
Recent additions:
since ago